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Thermochemistry measures heat involved in reactions: ΔH (enthalpy change), ΔS (entropy change), ΔG (Gibbs free energy).
Trin-for-trin guide
- 1Input reaction and temperature
- 2Calculate ΔH from bond energies or Hess's law
- 3Determine spontaneity: ΔG = ΔH - TΔS
Løste eksempler
Input
Combustion: exothermic (ΔH < 0), entropy increases (ΔS > 0)
Resultat
Spontaneous at all temperatures (ΔG < 0)
Almindelige fejl at undgå
- ✕Assuming exothermic always spontaneous
- ✕Not accounting for temperature dependence
Ofte stillede spørgsmål
When is reaction spontaneous?
ΔG < 0; depends on temperature through ΔH - TΔS balance.
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